Check 21, which became effective Oct. 28, 2004 allows for substitute checks to be legal replacements for the actual check you wrote. This replacement document now paves the way for banks to clear checks electronically. However, it is a huge investment in technology and not many banks are entering the fray.
For the "instantaneous" clearing, every stop along the way of check clearing has to be electronic. The merchant, the bank of first deposit, any intermediary bank, and so on.
It can happen and someday it will, but not anytime soon.
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I try to take one day at a time -- but sometimes several days attack me at once.